福建政和县东际金（银）矿床黄铁矿微量元素和硫-铅同位素及锆石年龄研究     

肖凡  班宜忠  范飞鹏  许乃岑  毛光武  李凤春 《中国地质》2020,47(2):375-393

东际金(银)矿床赋存于燕山晚期南园组火山岩中,是东南沿海地区一个隐爆角砾岩型贵金属矿床,已探明金资源量达12.5 t,银资源量135.9 t。通过开展主要金属硫化物黄铁矿电子探针和硫-铅同位素分析,讨论了成矿作用和成矿物质来源等问题。研究表明,东际金(银)矿床黄铁矿Co/Ni值3～94(平均值23)且Co含量为500×10-6～1070×10-6(均值799×10-6),Fe/(S+As)值0.827～0.871(均值0.860),Au/Ag值0.9～5.5(均值2.6),反映该矿床是与陆相火山作用有关的浅成中低温热液型矿床。黄铁矿δ34S在-6.6‰～-0.7‰,206Pb/204Pb为17.9801～18.4303,207Pb/204Pb为15.2689～15.9397,208Pb/204Pb为37.9052～38.7871,指示成矿物质主要来源于具有壳幔混源性质的花岗质岩浆,此外含矿热液也活化萃取了部分基底变质岩和火山岩围岩的金属元素。通过锆石U-Pb年代学研究和区域成矿资料对比,东际金(银)矿床成矿时代可被限定于早白垩世晚期。  相似文献   

Radiolarian‐based study on the fabric and the formation process of the Early Cretaceous mélange near Zhongba,Yarlung–Tsangpo Suture Zone,southern Tibet     

Xin Li  Atsushi Matsuoka  Yalin Li  Yushuai Wei  Chengshan Wang 《Island Arc》2019,28(1)

The Yarlung–Tsangpo Suture Zone (YTSZ), as the southernmost and youngest among the sutures that subdivides the Tibetan Plateau into several east–west trending blocks, marks where the Neo‐Tethys was consumed as the Indian continent moved northward and collided against the Eurasian continent. Mélanges in the YTSZ represent the remnants of the oceanic plate through subduction and collision. Mélanges are characterized by a highly sheared volcanoclastic or siliceous mudstone matrix including blocks of chert, claystone, and basalt. Detailed radiolarian analyses are conducted on the mélange near Zhongba County. Macroscopic, mesoscopic, and microscopic observations are combined in order to elucidate the relationships among age, lithology, and structure of blocks in the mélange. Reconstructed ocean plate stratigraphy includes Lower Jurassic limestone within the chert sequence accumulated at a depth near the CCD (Unit 2), Upper Jurassic thin‐bedded chert interbedded with claystone deposited in the wide ocean basin (Unit 3), and Lower Cretaceous chert with siliceous mudstone (Units 4 and 5), representing the middle parts of ocean plate stratigraphy. The results highlight the fabric of brecciated chert on mesoscopic scale, which is thought to be due to localized overpressure. The formation of mesoscopic and microscopic block‐in‐matrix fabrics in the mélange is proposed for the chert and siliceous mudstone bearing different extents of consolidation and competence during the progressive deformation of accreted sediments at shallow‐level subduction.  相似文献   

南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪   总被引：1，自引：1，他引：0  

张美  陆红锋  管红香  刘丽华  邬黛黛  吴能友 《海洋学报(英文版)》2018,37(7):20-27

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.  相似文献   

几内亚福雷卡里亚YML铁矿区的富铁矿床地质特征及找矿前景探讨          下载免费PDF全文

江胜国  李宏臣  付方建  王志刚  曹健 《地质找矿论丛》2018,33(1):142-148

YML铁矿区位于几内亚福雷卡里亚省,富铁矿以条带状赤铁矿和铁角砾岩矿为主。矿区内共发育7条矿体,条带状赤铁矿体6条,铁角砾岩矿体1条。条带状赤铁矿体赋存部位多为向形地段,次级紧密褶皱发育,沿走向和倾向有逐渐变薄和尖灭的趋势;铁角砾岩矿体覆盖于地表,以风化壳的形式出现。矿床类型属复合类型,即海底热液喷气沉积叠加后期构造变质型+风化淋滤型。该区具备铁矿形成和保存的地质条件,且已发现具一定储量、品位较高的条带状赤铁矿和大面积的铁角砾岩分布区,区内铁矿找矿远景较好。  相似文献   

东濮凹陷膏盐岩对烃源岩成烃演化的控制作用及其石油地质意义     

陈湘飞  李素梅  张洪安  徐田武  张云献  万中华  纪红  郭振乾 《现代地质》2018,32(6):1125

东濮凹陷北部盐湖相膏盐岩极其发育,膏盐岩对烃源岩性质及生烃特征的影响研究薄弱。采用地质与地球化学相结合途径,探讨了含膏盐岩层系烃源岩特性及其成烃演化规律。结果表明,盐区与无盐区烃源岩的特性有很大差异,北部盐湖相含盐区深灰色、褐色等暗色页岩有机质丰度一般大于15%,有机质类型以Ⅱ1型和Ⅰ型为主,是区内主要的优质烃源岩;南部淡水湖相无盐区主要发育有利生气的Ⅱ—Ⅲ型干酪根,反映东濮凹陷烃源岩的质量及生烃潜能与膏盐岩的发育密切相关。观察到膏盐岩影响烃源岩的成烃演化进程,当膏盐层厚度为50 m时,生油窗的范围显著增加;随着盐岩厚度(>50 m)的增加,湿气窗的范围也逐渐增加;当膏盐岩厚度约400 m时,生油窗范围开始减小,湿气窗的范围仍有增加趋势。膏盐岩对烃源岩“生油气窗”的影响是基于其较高的热导率属性,通过影响地温场而实现。以地质解剖为依据,建立了文留地区含膏盐岩层系烃源岩成烃演化模式。东濮凹陷含膏盐岩层系烃源岩的演化特征对该凹陷及同类含膏盐岩盆地油气勘探具有重要指示意义。  相似文献   

江西李公岭花岗闪长岩锆石U-Pb定年及找矿前景     

戴盼  吴胜华  宋世伟  项新葵 《世界地质》2018,37(2):409-422

为探究江西李公岭花岗闪长岩的成岩时代和成矿前景,对李公岭地区的花岗闪长岩及其中发育的隐爆角砾岩筒中的花岗闪长(斑)岩角砾岩块分别进行了锆石LA-ICP-MS U-Pb定年。测年结果表明,李公岭花岗闪长岩(150.6±1.1)Ma和隐爆角砾岩筒中的花岗闪长(斑)岩岩块(151.0±1.3)Ma基本为同时形成,时代为晚侏罗世。李公岭花岗闪长岩和李公岭角砾岩筒中的花岗闪长(斑)岩的形成时代与区内发育的阳储岭W-Mo矿的成岩成矿时代基本一致,以及隐爆角砾岩筒和周围的网脉状石英脉的存在,表明李公岭地区当时可能存在一个岩浆热液活动中心,且该热液活动可能与江南古陆东北缘燕山晚期大规模W-Mo成矿作用有关,暗示李公岭岩体周围具有较大的W-Mo找矿前景。  相似文献   

陕西略阳张家山金矿成矿作用及Au-Se矿物形成物理化学条件研究     

谭毓雯  朱永峰  蒋久阳 《矿床地质》2018,37(4):729-750

陕西略阳煎茶岭金矿矿集区中的张家山金矿主要由破碎蚀变岩型、角砾岩型和含金石英黄铁矿脉型矿石组成。含金石英-黄铁矿脉型矿石产于断层下盘的石英菱镁岩中。黄铁矿发育富As黄铁矿边,环边受As含量的变化呈现一定的韵律变化,自然金赋存在富As黄铁矿中。在断裂发育形成断层角砾岩的过程中,流体充填破碎石英菱镁岩的裂隙中形成热液矿物,包括硫化物、硒化物以及自然金。石英菱镁岩发生破碎形成的网状裂隙被含金石英-方解石-黄铁矿脉充填。破碎蚀变岩型矿石中,自然金主要分布在含金石英-黄铁矿脉的石英之中或靠近热液脉的菱镁矿或石英间隙。随着大量方解石脉沿裂隙贯入,进一步促进石英菱镁岩的破碎及岩石角砾的分离,形成由石英菱镁岩碎屑、石英和褐铁矿组成的复成分角砾岩,自然金和硒化物呈浸染状分布在角砾岩中。笔者在角砾岩型矿石中发现了灰硒汞矿、直硒镍矿、硒铅矿等硒化物,这些硒化物往往与自然金密切共生。结合矿物组合以及相关化学反应关系,通过热力学计算,构建了该矿床在不同温度条件下的热力学相平衡关系图,限定了硒化物与其他相关矿物稳定存在的物理化学条件。硒化物一般与自然金和石英共生,高的f(Se2)值和f(Se2)/f(S2)比值是控制硒化物形成的关键因素。  相似文献   

小兴安岭霍吉河钼矿床成矿过程——透岩浆成矿作用     

王泉  刘东舟  郭鸿斌 《地质与资源》2018,27(3):243-250

传统上将小兴安岭霍吉河钼矿床归类为斑岩型钼矿.通过对矿区地质特征的研究,即矿区无斑岩体、矿体围绕隐爆角砾岩呈环状出露、石英细脉-网脉状和浸染状矿石结构、成矿年龄明显晚于赋矿围岩形成时间等,认为该矿床是透岩浆成矿作用的结果.早中生代伊春-延寿花岗岩岩基带上相伴的大型-超大型钼矿是典型的透岩浆成矿作用的产物,是岩基后成矿作用.  相似文献   

黔西南水银洞爆破角砾岩筒与金元素超常富集     

邱小平  刘世川  魏密 《地球学报》2021,42(6):849-858

水银洞金矿床曾被认为是滇黔桂地区最有代表性的微细浸染型金矿(卡林型金矿),然而矿床的金品位明显高于一般意义上的卡林型金矿床,且金矿体与气液爆破角砾岩关系密切.气液爆破角砾岩呈垂直筒状产状,两侧断裂矿化带呈向上扩张的"喇叭口"状成矿空间,富金矿体紧密围绕角砾岩筒分布.根据野外和显微镜观察,角砾岩块成分复杂与显著磨圆.气液角砾岩筒的角砾岩显著富集金、稀土、亲地幔过渡元素Ti、Cr、Ni、Co、V等,以及Zr、Hf等,明显地区别于围岩,反映出深源流体快速上升的气液爆破角砾岩的特征,角砾岩筒实际上具备含金成矿流体的上涌通道的功能.岩筒中早期角砾岩的角砾含Au达18×10–6,属于深部金矿体的爆破碎块,显示出水银洞金矿床可观的深部找矿勘探前景.  相似文献   

滇中地区因民角砾岩类型、特征及找矿意义     

刘军平  宛胜  戴启  田素梅  赵江泰  吴嘉林 《地质论评》2021,67(6):1619-1628

滇中地区“因民角砾岩”的成因及归属问题目前暂无定论。笔者通过对东川-易门地区前人所划的因民组“因民角砾岩”进行1：5万野外地质调查工作,对其进行了初步的分类。根据其成因及时代划分为复成分砾岩、冰碛砾岩、滑塌角砾岩、引爆角砾岩和构造角砾岩。对“因民角砾岩”成因及时代的研究,特别是“冰碛砾岩、复成分砾岩”的提出,对于解决滇中早前寒武纪地层层序、时代归属、构造格架、大地构造位置及大区域地层对比,探讨滇中元古宙地史演化、古环境研究以及指导找矿都具有重要的指示意义。  相似文献